Preprints
https://doi.org/10.5194/mr-2021-55
https://doi.org/10.5194/mr-2021-55

  12 Jul 2021

12 Jul 2021

Review status: a revised version of this preprint was accepted for the journal MR and is expected to appear here in due course.

Spin-Noise Gradient Echoes

Victor V. Rodin1, Stephan J. Ginthör1, Matthias Bechmann1, Hervé Desvaux2, and Norbert Müller1,3 Victor V. Rodin et al.
  • 1Institute of Organic Chemistry, Johannes Kepler University Linz, Altenbergerstraße 69, 4040 Linz, Austria
  • 2NIMBE, CEA, CNRS, Université Paris-Saclay, CEA/Saclay, 91191 Gif-sur-Yvette, France
  • 3Faculty of Science, University of South Bohemia in České Budějovice, Branišovská 1645/31a, 370 05 České Budějovice, Czech Republic

Abstract. Nuclear spin-noise spectroscopy in absence of radio frequency pulses was studied under the influence of pulsed field gradients (PFGs) on pure and mixed liquids. Under conditions, where the radiation-damping induced line broadening is smaller than the gradient dependent inhomogeneous broadening, echo responses can be observed in difference spectra between experiments employing pulsed field gradient pairs of same and opposite signs. These observed “spin-noise gradient echoes” (SNGEs) were analyzed through a simple model to describe the effects of transient phenomena. Experiments performed on high resolution NMR probes demonstrate how “refocused spin noise” behaves and how it can be exploited to determine sample properties. In bulk liquids and their mixtures transverse relaxation times as well as translational diffusion constants can be determined from SNGE spectra recorded following tailored sequences of magnetic field gradient pulses.

Victor V. Rodin et al.

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on mr-2021-55', Anonymous Referee #1, 21 Jul 2021
    • AC1: 'Reply on RC1', Norbert Mueller, 21 Jul 2021
      • RC2: 'Reply on AC1', Anonymous Referee #1, 21 Jul 2021
  • RC3: 'Comment on mr-2021-55', Anonymous Referee #2, 16 Sep 2021

Status: closed

Comment types: AC – author | RC – referee | CC – community | EC – editor | CEC – chief editor | : Report abuse
  • RC1: 'Comment on mr-2021-55', Anonymous Referee #1, 21 Jul 2021
    • AC1: 'Reply on RC1', Norbert Mueller, 21 Jul 2021
      • RC2: 'Reply on AC1', Anonymous Referee #1, 21 Jul 2021
  • RC3: 'Comment on mr-2021-55', Anonymous Referee #2, 16 Sep 2021

Victor V. Rodin et al.

Victor V. Rodin et al.

Viewed

Total article views: 364 (including HTML, PDF, and XML)
HTML PDF XML Total Supplement BibTeX EndNote
279 69 16 364 36 10 16
  • HTML: 279
  • PDF: 69
  • XML: 16
  • Total: 364
  • Supplement: 36
  • BibTeX: 10
  • EndNote: 16
Views and downloads (calculated since 12 Jul 2021)
Cumulative views and downloads (calculated since 12 Jul 2021)

Viewed (geographical distribution)

Total article views: 340 (including HTML, PDF, and XML) Thereof 340 with geography defined and 0 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 
Latest update: 21 Oct 2021
Download
Short summary
We provide a proof of concept that relaxation and diffusion parameters can be determined from nuclear spin noise spectra acquired with customizable sequences of switched magnetic field gradients. The methods do not require any excitation with a radio frequency source.