Magnetic Resonance
Magnetic Resonance
MR
Articles | Volume 1, issue 2
Articles | Volume 1, issue 2
https://doi.org/10.5194/mr-1-197-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/mr-1-197-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 1, issue 2
Research article
 | 
10 Sep 2020
Research article |  | 10 Sep 2020

EPR study of NO radicals encased in modified open C60 fullerenes

Klaus-Peter Dinse, Tatsuhisa Kato, Shota Hasegawa, Yoshifumi Hashikawa, Yasujiro Murata, and Robert Bittl

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Cited articles

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Chiesa, M., Giamello, E., and Che, M.: EPR Characterization and Reactivity of Surface-Localized Inorganic Radicals and Radical Ions, Chem. Rev., 110, 1320–1347, 2010. a
Dinse, K.-P., Kato, T., Hasegawa, S., Hashikawa, Y., Murata, Y., and Bittl, R.: Experimental data set and further information, Refubium – Freie Universität Berlin Repository, https://doi.org/10.17169/refubium-27870, 2020. a
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The stable, two-atomic radical NO, which is an important biophysical messenger, was studied with magnetic resonance methods. Caused by its specific electronic configuration, it has sensor properties: its magnetic moment sensitively depends on its environment and restricted mobility therein. The interaction with solvents or solid phases can thus be quantified. Encapsulating the radical in the nearly spherical cage of modified C60 fullerenes is a perfect situation to study this effect.
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