Magnetic Resonance
Magnetic Resonance
MR
Articles | Volume 4, issue 2
Articles | Volume 4, issue 2
https://doi.org/10.5194/mr-4-217-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/mr-4-217-2023
© Author(s) 2023. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 4, issue 2
Research article
 | 
24 Aug 2023
Research article |  | 24 Aug 2023

Asymmetry in three-site relaxation exchange NMR

Bernhard Blümich, Matthew Parziale, and Matthew Augustine

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Latest update: 23 Apr 2025
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Short summary
Diffusive motion in confined three-site relaxation exchange was studied in Monte Carlo simulations. In thermodynamic equilibrium, the cross-peaks in NMR relaxation exchange maps are symmetric. Asymmetry is observed in mass-balanced driven equilibrium corresponding to circular flow. If this motion can be stimulated by external forces, it can be beneficial to heterogeneous catalysis.
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