Articles | Volume 1, issue 1
https://doi.org/10.5194/mr-1-13-2020
https://doi.org/10.5194/mr-1-13-2020
Research article
 | 
19 Feb 2020
Research article |  | 19 Feb 2020

Origin of the residual line width under frequency-switched Lee–Goldburg decoupling in MAS solid-state NMR

Johannes Hellwagner, Liam Grunwald, Manuel Ochsner, Daniel Zindel, Beat H. Meier, and Matthias Ernst

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Latest update: 21 Nov 2024
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Short summary
This paper analyzes a commonly used line-narrowing mechanism (homonuclear decoupling) in solid-state NMR and discusses what limits the achievable line width. Based on theoretical considerations, the contribution of different effects to the line width is discussed and a new contributing term is identified. This research allows us to evaluate new ways to improve the line width in such homonuclear decoupled spectra.