Articles | Volume 1, issue 2
Magn. Reson., 1, 175–186, 2020
https://doi.org/10.5194/mr-1-175-2020
Magn. Reson., 1, 175–186, 2020
https://doi.org/10.5194/mr-1-175-2020
Research article
07 Aug 2020
Research article | 07 Aug 2020

Geminal parahydrogen-induced polarization: accumulating long-lived singlet order on methylene proton pairs

Laurynas Dagys et al.

Viewed

Total article views: 1,164 (including HTML, PDF, and XML)
HTML PDF XML Total Supplement BibTeX EndNote
688 423 53 1,164 467 37 37
  • HTML: 688
  • PDF: 423
  • XML: 53
  • Total: 1,164
  • Supplement: 467
  • BibTeX: 37
  • EndNote: 37
Views and downloads (calculated since 26 Jun 2020)
Cumulative views and downloads (calculated since 26 Jun 2020)

Viewed (geographical distribution)

Total article views: 1,131 (including HTML, PDF, and XML) Thereof 1,129 with geography defined and 2 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 

Cited

Latest update: 08 Aug 2022
Download
Short summary
We explored hydrogenation reaction with a para-spin isomer of a hydrogen molecule as a source of nuclear singlet state. As a product of this reaction, the state was populated between two protons of the methylene group. We have shown that, utilizing long-lived properties of such a nuclear spin state, a high nuclear spin polarization can be accumulated. To explain this effect we have given a kinetic model which could be potentially applied for similar schemes involving spin dynamics in chemistry.