Magnetic Resonance
Magnetic Resonance
MR
Articles | Volume 2, issue 1
Articles | Volume 2, issue 1
https://doi.org/10.5194/mr-2-139-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/mr-2-139-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 2, issue 1
Research article
 | 
13 Apr 2021
Research article |  | 13 Apr 2021

Exchange interaction in short-lived flavine adenine dinucleotide biradical in aqueous solution revisited by CIDNP (chemically induced dynamic nuclear polarization) and nuclear magnetic relaxation dispersion

Ivan V. Zhukov, Alexey S. Kiryutin, Mikhail S. Panov, Natalya N. Fishman, Olga B. Morozova, Nikita N. Lukzen, Konstantin L. Ivanov, Hans-Martin Vieth, Renad Z. Sagdeev, and Alexandra V. Yurkovskaya

Viewed

Total article views: 1,276 (including HTML, PDF, and XML)
HTML PDF XML Total BibTeX EndNote
702 529 45 1,276 26 23
  • HTML: 702
  • PDF: 529
  • XML: 45
  • Total: 1,276
  • BibTeX: 26
  • EndNote: 23
Views and downloads (calculated since 16 Feb 2021)
Cumulative views and downloads (calculated since 16 Feb 2021)

Viewed (geographical distribution)

Total article views: 1,276 (including HTML, PDF, and XML) Thereof 1,141 with geography defined and 135 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 
Latest update: 31 Mar 2023
Download
Short summary
We report data on nuclear polarization formed in photoreaction of intramolecular electron transfer from adenine to flavin that was revealed several years ago by R. Kaptein by CIDNP. The question of whether one or two types of biradicals are formed stays unresolved. This work clarified the problem and confirmed that single common emissive maximum in magnetic field dependence of CIDNP may originate from single level crossing of short-lived biradical and that the FAD molecule has a compact shape.
Read more
Special issue
Robert Kaptein Festschrift