Articles | Volume 2, issue 1
https://doi.org/10.5194/mr-2-265-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/mr-2-265-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
An electrochemical cell for in operando 13C nuclear magnetic resonance investigations of carbon dioxide/carbonate processes in aqueous solution
Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich, Jülich, Germany
Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Aachen, Germany
P. Philipp M. Schleker
Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich, Jülich, Germany
Department of Heterogeneous Reactions, Max Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr, Germany
Matthias Streun
Central Institute of Engineering and Analytics, Electronic Systems (ZEA-2), Forschungszentrum Jülich, Jülich, Germany
Steffen Merz
Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich, Jülich, Germany
Peter Jakes
Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich, Jülich, Germany
Michael Schatz
Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich, Jülich, Germany
Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Aachen, Germany
Rüdiger-A. Eichel
Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich, Jülich, Germany
Institute of Physical Chemistry, RWTH Aachen University, Aachen, Germany
Josef Granwehr
Institute of Energy and Climate Research, Fundamental Electrochemistry (IEK-9), Forschungszentrum Jülich, Jülich, Germany
Institute of Technical and Macromolecular Chemistry, RWTH Aachen University, Aachen, Germany
Viewed
Total article views: 2,634 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 15 Feb 2021)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
1,621 | 944 | 69 | 2,634 | 56 | 48 |
- HTML: 1,621
- PDF: 944
- XML: 69
- Total: 2,634
- BibTeX: 56
- EndNote: 48
Total article views: 1,834 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 06 May 2021)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
1,171 | 615 | 48 | 1,834 | 50 | 45 |
- HTML: 1,171
- PDF: 615
- XML: 48
- Total: 1,834
- BibTeX: 50
- EndNote: 45
Total article views: 800 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 15 Feb 2021)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
450 | 329 | 21 | 800 | 6 | 3 |
- HTML: 450
- PDF: 329
- XML: 21
- Total: 800
- BibTeX: 6
- EndNote: 3
Viewed (geographical distribution)
Total article views: 2,634 (including HTML, PDF, and XML)
Thereof 2,384 with geography defined
and 250 with unknown origin.
Total article views: 1,834 (including HTML, PDF, and XML)
Thereof 1,690 with geography defined
and 144 with unknown origin.
Total article views: 800 (including HTML, PDF, and XML)
Thereof 694 with geography defined
and 106 with unknown origin.
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Cited
10 citations as recorded by crossref.
- Combined method electrochemistry—NMR. From the past to the future V. Mairanovsky 10.1007/s10008-021-05048-z
- In operando NMR investigations of the aqueous electrolyte chemistry during electrolytic CO2 reduction S. Jovanovic et al. 10.1038/s42004-023-01065-3
- Direct Imaging of Local pH Reveals Bubble-Induced Mixing in a CO2 Electrolyzer L. Baumgartner et al. 10.1021/acssuschemeng.3c01773
- A parallel line probe for spatially selective electrochemical NMR spectroscopy R. Luo et al. 10.1016/j.jmr.2024.107666
- Workflow for systematic design of electrochemical in operando NMR cells by matching B0 and B1 field simulations with experiments M. Schatz et al. 10.5194/mr-5-167-2024
- Interplay of Local pH and Cation Hydrolysis during Electrochemical CO2 Reduction Visualized by In Operando Chemical Shift-Resolved Magnetic Resonance Imaging M. Schatz et al. 10.1021/acs.jpcc.3c03563
- Compact In Situ Electrochemical NMR with Wireless and Anti-interference Strategy in Multiscenario Applications L. Wang et al. 10.1021/acs.analchem.4c00807
- Quantifying local pH changes in carbonate electrolyte during copper-catalysed $$\hbox {CO}_2$$ electroreduction using in operando $$^{13}\hbox {C}$$ NMR M. Schatz et al. 10.1038/s41598-022-12264-8
- Spatio‐Temporal Electrowetting and Reaction Monitoring in Microfluidic Gas Diffusion Electrode Elucidates Mass Transport Limitations S. Brosch et al. 10.1002/smll.202310427
- Operando electrochemical NMR spectroscopy reveals a water-assisted formate formation mechanism B. Xu et al. 10.1016/j.chempr.2024.06.001
10 citations as recorded by crossref.
- Combined method electrochemistry—NMR. From the past to the future V. Mairanovsky 10.1007/s10008-021-05048-z
- In operando NMR investigations of the aqueous electrolyte chemistry during electrolytic CO2 reduction S. Jovanovic et al. 10.1038/s42004-023-01065-3
- Direct Imaging of Local pH Reveals Bubble-Induced Mixing in a CO2 Electrolyzer L. Baumgartner et al. 10.1021/acssuschemeng.3c01773
- A parallel line probe for spatially selective electrochemical NMR spectroscopy R. Luo et al. 10.1016/j.jmr.2024.107666
- Workflow for systematic design of electrochemical in operando NMR cells by matching B0 and B1 field simulations with experiments M. Schatz et al. 10.5194/mr-5-167-2024
- Interplay of Local pH and Cation Hydrolysis during Electrochemical CO2 Reduction Visualized by In Operando Chemical Shift-Resolved Magnetic Resonance Imaging M. Schatz et al. 10.1021/acs.jpcc.3c03563
- Compact In Situ Electrochemical NMR with Wireless and Anti-interference Strategy in Multiscenario Applications L. Wang et al. 10.1021/acs.analchem.4c00807
- Quantifying local pH changes in carbonate electrolyte during copper-catalysed $$\hbox {CO}_2$$ electroreduction using in operando $$^{13}\hbox {C}$$ NMR M. Schatz et al. 10.1038/s41598-022-12264-8
- Spatio‐Temporal Electrowetting and Reaction Monitoring in Microfluidic Gas Diffusion Electrode Elucidates Mass Transport Limitations S. Brosch et al. 10.1002/smll.202310427
- Operando electrochemical NMR spectroscopy reveals a water-assisted formate formation mechanism B. Xu et al. 10.1016/j.chempr.2024.06.001
Latest update: 13 Dec 2024
Short summary
This work presents a setup for the investigation of electrochemical processes during operation (in operando) using nuclear magnetic resonance (NMR) spectroscopy. The setup was designed to minimize the interferences between the NMR instrument and the electrochemical equipment. Employing this setup, the dynamic equilibrium of carbon dioxide in aqueous bicarbonate electrolyte has been monitored in operando, revealing intercations with the electrode setup.
This work presents a setup for the investigation of electrochemical processes during operation...