Magnetic Resonance
Magnetic Resonance
MR
Articles | Volume 6, issue 2
Articles | Volume 6, issue 2
https://doi.org/10.5194/mr-6-273-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/mr-6-273-2025
© Author(s) 2025. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 6, issue 2
Research article
 | 
24 Nov 2025
Research article |  | 24 Nov 2025

Long-lived states involving a manifold of fluorine-19 spins in fluorinated aliphatic chains

Coline Wiame, Sebastiaan Van Dyck, Kirill Sheberstov, Aiky Razanahoera, and Geoffrey Bodenhausen

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Short summary
In achiral polyfluoroalkyl substances with two to three CF₂ groups, long-lived ¹⁹F spin states (TLLS) were measured and found to last about three times longer than T₁ in a static 11.6 T field. These lifetimes are sensitive to macromolecular binding, making them useful for screening fluorinated drugs.
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