Institute of Organic Chemistry and Institute for Biological Interfaces 4 – Magnetic Resonance, Karlsruhe Institute of Technology (KIT), Kaiserstr. 12, 76131 Karlsruhe, Germany
Institute of Organic Chemistry and Institute for Biological Interfaces 4 – Magnetic Resonance, Karlsruhe Institute of Technology (KIT), Kaiserstr. 12, 76131 Karlsruhe, Germany
Bilinear rotations like BIRD, TANGO, BANGO, and BIG-BIRD are essential building blocks in modern nuclear magnetic resonance (NMR) spectroscopy that allow the rotation of an isolated spin without couplings (i.e., bilinear interactions) in one way, while rotating spins with a matched coupling in another way. Two ways for constructing particularly robust bilinear rotations (compensated for couplings, offsets, and B1 inhomogeneities, or COB/COB3) are provided and demonstrated in both theory and experiment.
Bilinear rotations like BIRD, TANGO, BANGO, and BIG-BIRD are essential building blocks in modern...