Univ. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, Lille, 59000, France
Andrew G. M. Rankin
Univ. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, Lille, 59000, France
present address: Sorbonne Université, CNRS, Collège de
France, Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP), 4 place Jussieu, Paris, 75005, France
Univ. Lille, CNRS, INRAE, Centrale Lille, Univ. Artois, FR 2638 –
IMEC – Fédération Chevreul, Lille, 59000, France
Frédérique Pourpoint
Univ. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, Lille, 59000, France
Yu Tsutsumi
Bruker Japan, 3-9 Moriya, Kanagawa, Yokohama, Kanagawa,
221-0022, Japan
Hiroki Nagashima
Interdisciplinary Research Center for Catalytic Chemistry, National
Institute of Advanced Industrial Science and Technology (AIST), 1-1-1
Higashi, Tsukuba, Ibaraki, 305-8565, Japan
The transfer of polarization from protons to half-integer spin quadrupolar nuclei provides insights into the proximities between these nuclei. We analyse the best transfers at 20 and 62 kHz MAS obtained with RINEPT and PRESTO recouplings using adiabatic or composite π pulses. The 1H magnetization is best transferred using PRESTO-R22,7,2 (180) or -R16,6,7 (270,90) at 20 or 62 kHz MAS, respectively, and RINEPT-SR4,2,1 (270,90).
The transfer of polarization from protons to half-integer spin quadrupolar nuclei provides...
