Magnetic Resonance
Magnetic Resonance
MR
Articles | Volume 2, issue 1
Articles | Volume 2, issue 1
https://doi.org/10.5194/mr-2-93-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/mr-2-93-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 2, issue 1
Research article
 | 
08 Apr 2021
Research article |  | 08 Apr 2021

Pd-based bimetallic catalysts for parahydrogen-induced polarization in heterogeneous hydrogenations

Dudari B. Burueva, Aleksandr Y. Stakheev, and Igor V. Koptyug

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Short summary
Catalytic hydrogenation of unsaturated molecular precursors with parahydrogen provides a major signal enhancement in NMR, which is vital for many technical as well as biomedical applications. We show that dilution of catalytically active Pd with a less active metal in heterogeneous Pd-based catalysts provides significantly larger enhancements and that the judicious choice of the dilution metal can further improve the performance, as revealed by comparing Pd-Ag and Pd-In bimetallic catalysts.
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