Articles | Volume 4, issue 1
https://doi.org/10.5194/mr-4-153-2023
https://doi.org/10.5194/mr-4-153-2023
Research article
 | 
05 Jun 2023
Research article |  | 05 Jun 2023

The solid effect of dynamic nuclear polarization in liquids

Deniz Sezer

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Short summary
We show that the field profile of the solid effect in liquids is rich in dynamical information, including about timescales of molecular diffusion. We develop a general theoretical framework for extracting this information through quantitative fits to the experimental data. Unusual peaks in the enhancement field profile, which resemble thermal mixing but are not related to it, are demonstrated to arise in liquids under some conditions. These additionally restrict the dynamical parameters.