Magnetic Resonance
Magnetic Resonance
MR
Articles | Volume 5, issue 2
Articles | Volume 5, issue 2
https://doi.org/10.5194/mr-5-167-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/mr-5-167-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 5, issue 2
Research article
 | 
20 Nov 2024
Research article |  | 20 Nov 2024

Workflow for systematic design of electrochemical in operando NMR cells by matching B0 and B1 field simulations with experiments

Michael Schatz, Matthias Streun, Sven Jovanovic, Rüdiger-A. Eichel, and Josef Granwehr

Related authors

An electrochemical cell for in operando 13C nuclear magnetic resonance investigations of carbon dioxide/carbonate processes in aqueous solution
Sven Jovanovic, P. Philipp M. Schleker, Matthias Streun, Steffen Merz, Peter Jakes, Michael Schatz, Rüdiger-A. Eichel, and Josef Granwehr
Magn. Reson., 2, 265–280, https://doi.org/10.5194/mr-2-265-2021,https://doi.org/10.5194/mr-2-265-2021, 2021
Short summary

Related subject area

Field: Liquid-state NMR | Topic: Instrumentation
A portable NMR platform with arbitrary phase control and temperature compensation
Qing Yang, Jianyu Zhao, Frederik Dreyer, Daniel Krüger, and Jens Anders
Magn. Reson., 3, 77–90, https://doi.org/10.5194/mr-3-77-2022,https://doi.org/10.5194/mr-3-77-2022, 2022
Short summary
Magnetostatic reciprocity for MR magnet design
Pedro Freire Silva, Mazin Jouda, and Jan G. Korvink
Magn. Reson., 2, 607–617, https://doi.org/10.5194/mr-2-607-2021,https://doi.org/10.5194/mr-2-607-2021, 2021
Short summary
An electrochemical cell for in operando 13C nuclear magnetic resonance investigations of carbon dioxide/carbonate processes in aqueous solution
Sven Jovanovic, P. Philipp M. Schleker, Matthias Streun, Steffen Merz, Peter Jakes, Michael Schatz, Rüdiger-A. Eichel, and Josef Granwehr
Magn. Reson., 2, 265–280, https://doi.org/10.5194/mr-2-265-2021,https://doi.org/10.5194/mr-2-265-2021, 2021
Short summary
Overhauser dynamic nuclear polarization (ODNP)-enhanced two-dimensional proton NMR spectroscopy at low magnetic fields
Timothy J. Keller and Thorsten Maly
Magn. Reson., 2, 117–128, https://doi.org/10.5194/mr-2-117-2021,https://doi.org/10.5194/mr-2-117-2021, 2021
Short summary
ArduiTaM: accurate and inexpensive NMR auto tune and match system
Mazin Jouda, Saraí M. Torres Delgado, Mehrdad Alinaghian Jouzdani, Dario Mager, and Jan G. Korvink
Magn. Reson., 1, 105–113, https://doi.org/10.5194/mr-1-105-2020,https://doi.org/10.5194/mr-1-105-2020, 2020
Short summary

Cited articles

Aguilera, A. R., MacMillan, B., Krachkovskiy, S., Sanders, K. J., Alkhayri, F., Adam Dyker, C., Goward, G. R., and Balcom, B. J.: A parallel-plate RF probe and battery cartridge for 7Li ion battery studies, J. Magn. Reson., 325, 106943, https://doi.org/10.1016/j.jmr.2021.106943, 2021. a
Bazak, J. D., Allen, J. P., Krachkovskiy, S. A., and Goward, G. R.: Mapping of Lithium-Ion Battery Electrolyte Transport Properties and Limiting Currents with In Situ MRI, J. Electrochem. Soc., 167, 140518, https://doi.org/10.1149/1945-7111/abc0c9, 2020. a, b
Benders, S., Gomes, B. F., Carmo, M., Colnago, L. A., and Blümich, B.: In-situ MRI velocimetry of the magnetohydrodynamic effect in electrochemical cells, J. Magn. Reson., 312, 106692, https://doi.org/10.1016/j.jmr.2020.106692, 2020. a
Bhattacharyya, R., Key, B., Chen, H., Best, A. S., Hollenkamp, A. F., and Grey, C. P.: In situ NMR observation of the formation of metallic lithium microstructures in lithium batteries, Nat. Mater., 9, 504–510, https://doi.org/10.1038/nmat2764, 2010. a
Borzutzki, K. and Brunklaus, G.: Chapter Three – Magnetic Resonance Imaging Studies of the Spatial Distribution of Charge Carriers, in: Annual Reports on NMR Spectroscopy, edited by: Webb, G. A., Vol. 91, 115–141, Academic Press, ISBN 0066-4103, https://doi.org/10.1016/bs.arnmr.2016.12.003, 2017. a
More articles (34)
Download
Short summary
We developed a workflow using finite element methods to optimise electrochemical cell designs for in operando nuclear magnetic resonance by accurately matching magnetic field and radio frequency field simulations with experimental data. Guidelines for enhanced sensitivity and field homogeneity are given. A radio frequency amplification effect in coin cells is described by empirical formulae, which have the potential to improve spatial selectivity in future in operando applications.
Read more