1H-enhanced 103Rh NMR spectroscopy and relaxometry of 103Rh(acac)3 in solution

Harbor-Collins, Harry; Sabba, Mohamed; Leutzsch, Markus; Levitt, Malcolm H.

doi:https://doi.org/10.5194/mr-5-121-2024

Articles | Volume 5, issue 2

https://doi.org/10.5194/mr-5-121-2024

© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.

https://doi.org/10.5194/mr-5-121-2024

© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.

Articles | Volume 5, issue 2

Research article

|

30 Aug 2024

Research article |

| 30 Aug 2024

¹H-enhanced ¹⁰³Rh NMR spectroscopy and relaxometry of ¹⁰³Rh(acac)₃ in solution

Harry Harbor-Collins, Mohamed Sabba, Markus Leutzsch, and Malcolm H. Levitt

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Cited articles

Aaltonen, T., Ritala, M., and Leskelä, M.: ALD of Rhodium Thin Films from Rh ( Acac )₃ and Oxygen, Electrochem. Solid St., 8, C99, 2005. a

Bajo, S., Alférez, M. G., Alcaide, M. M., López-Serrano, J., and Campos, J.: Metal-Only Lewis Pairs of Rhodium with s, p and d-Block Metals, Chem.-Eur. J., 26, 16833–16845, 2020. a

Benn, R., Brenneke, H., and Reinhardt, R.-D.: ¹⁰³Rh-NMR Bei 9,4 T – Verbesserter Nachweis Infolge Verkürzter Relaxationszeiten Und Selektivem Polarisationstransfer / ¹⁰³Rh NMR at 9.4 T – Improved Signal Detection Due to Shortened Relaxation Times and Selective Polarisation Transfer, Z. Naturforsch. B, 40, 1763–1765, 1985. a, b

Brevard, C. and Schimpf, R.: Phosphorus-Irradiation INEPT Experiments on Spin-12 Metal Nuclides. Applications to ¹⁰³Rh, ¹⁸³W, and ⁵⁷Fe, J. Magn. Reson., 47, 528–534, 1982. a

Brevard, C., Van Stein, G. C., and Van Koten, G.: Silver-109 and Rhodium-103 NMR Spectroscopy with Proton Polarization Transfer, J. Am. Chem. Soc., 103, 6746–6748, 1981. a